Mark out the area around the grass that you want to kill with pegs and twine. If there are any plants nearby that you don't want to kill, make sure you give them a wide berth. The nitrogen from the manure will gradually seep into the soil and cover a slightly wider area than its original bounds so don't place the manure too close to anything else.
Spread the manure over the area of grass you want to kill in a thick layer, at least 6 to 8 inches and as evenly as possible.
Leave the manure for two to three weeks then scrape away a corner. If the grass is dead underneath, remove the manure and place it in a heap to compost for use as a soil nutrient.