Inspect the areas of the pool for tears in a lining or cracks in the concrete pool structure. If you find either of these, it will be the source of the leak, and an evaporation test probably isn't necessary.
Fill a 5-gallon bucket of water from your faucet or yard's water supply. Place it outside next to the pool.
Wait for the water to stop rocking back and forth. With the water still, use the marker to indicate the top of the bucket's water line.
Mark the water line somewhere on the inside of the pool as well. A dot will be sufficient. You just need a place to measure the water level.
Wait at least 24 hours for the most accurate reading. Be sure it doesn't rain. Measure the amount of water lost in both the pool and bucket. Be as accurate as possible. If you lost more water in the pool than the bucket, your pool unfortunately has a leak.