Connect the white wire on the power connector to the neutral wire in the junction box for both interconnected and stand-alone alarms.
Connect the black wire on the power connector to the hot wire in the junction box for both interconnected and stand-alone alarms.
Connect the orange wire on the power connector to the interconnect wire in the junction box for interconnected alarms. Repeat for each unit. Do not connect the orange wire to a hot or neutral wire. Ignore the orange wire if you are connecting a stand-alone alarm—just tuck it away.