Soak iron nails in a bowl of vinegar for a few days. Of course, nails aren’t purely “natural,” and store-bought vinegar may contain additives, but mining your own iron and producing acetic acid by fermenting ethanol probably is a bit too natural for most people, so using nails and vinegar should qualify as a “natural” process. This process will produce a gray or reddish-brown stain, depending on the iron content of the nails and how long you soak them. You also can allow the vinegar to partially evaporate to intensify the color.
Soak tobacco (chewing tobacco works well) in water and ammonia. Measure out equal amounts of ammonia and water and pour the mixture over a mound of tobacco in a bowl. Use a glass or plastic bowl. Metal will react with the vinegar in a metal bowl. Use just enough of the water-ammonia mixture to cover the tobacco. Let it soak for a couple days. This will produce a brown, even ebony, stain. Tea or walnut shells also can be used, or you can combine items to produce different shades.
Dip a brush into the mixtures after you’ve achieved the color you want. Brush the mixture onto a piece of wood and allow it to dry. This natural method produces a fairly weak color -- not at all like the vibrant and intense colors found with synthetic pigments and manufactured stains. Depending on the type of wood to which you’re applying the stain, and how much stain you apply, you’ll get various results. Fresh wood will produce richer, deeper colors. Older, dried wood will yield much subtler colors. Experiment with scrap pieces of wood before using this natural mixture on a piece of furniture or other cherished item. The colors can vary from a grayish color accompanied by a sheen-like quality to an almost black color.