Remove the door knobs, hinges and any other hardware on the door using a screwdriver. Put painter's tape around any window to protect it from the paint.
Rub the door with a stiff metal brush to remove as much of the chipping paint as possible.
Apply a paint remover designed for metal to the door using a rag or a bristle paint brush. Leave the remover on the door for the time specified in the directions. Scrape off the paint with a putty knife.
Neutralize the paint remover with the type of neutralizer recommended by the manufacturer. Vinegar is often used as a paint neutralizer.
Sand the door with 120-grit sandpaper to give it a rough surface to which the paint can cling. Wipe the door with a tack cloth to remove the sanding dust. Avoid scratching any grooves into the door as you sand.
Apply a metal primer to the door. Use an aerosol, spray-on primer or apply a primer with a bristle brush. Allow it to cure according to package directions. Use exterior-grade primer.
Paint the door using paint that is compatible with the chosen primer. Use a bristle brush and roller or spray can to apply the paint. Allow it to cure and apply a second coat. Use exterior-grade paint.