Lay down a thick layer of newspaper below the area to be painted. If you're working over grass, you'll want to protect your lawn from chemicals that might kill it.
Use fine wet/dry sandpaper dipped in mineral spirits and lightly sand the entire surface that is to be painted.
Allow the metal to dry.
Apply a primer designed specifically for galvanized surfaces. Check the manufacturer's recommendations - some suggest two coats with a sanding session in between.
Be sure to choose a paint that will hold up to the weather (see Related eHows).
Apply the paint with a sprayer for the most uniform coverage.