Clean the porcelain sink with detergent. Wipe away all dirt and grime using a clean sponge.
Pour an abrasive cleaner containing bleach atop of any stubborn stains and attempt to scrub them away.
Rinse the entire sink surface.
Sand all areas of the sink with medium-grit sandpaper. Also concentrate the sanding to any chipped areas of the sink. Sand the spot until the area is smooth and free of chips.
Dab a soft cloth with rubbing alcohol and clean the sand grit from the chipped area.
Squeeze a dab of the porcelain repair compound onto the edge of a razor blade, then smooth it over the damaged area. Scrape off any excess repair compound using the razor blade. Allow the compound to dry.
Remove excess repair compound from the damaged area using a cotton swab saturated with rubbing alcohol. Allow the compound to dry.
Tape off the areas around the sink, the drain and faucet with painter's tape.
Dry the sink surface with a towel to make sure there is no moisture left.
Apply the porcelain paint to the sink surface with a brush roller. Allow it to dry for two days before applying a second coat. Some manufacturers recommend three coats.