Remove the protective coating found on new galvanized wrought iron with a cleaner specifically made for cleaning metal, advises the Sherwin Williams website. Dip a nylon scrub brush in the cleaning solution and go over the entire piece of wrought iron. Take special care to remove the coating from joints and carvings. Paint won't adhere properly if the oily coating remains on the wrought iron.
Remove any rust on older wrought iron before painting. Clean flat surfaces with a steel brush or file. Use coarse sandpaper to clean ornate, curved areas. Wipe clean with a soft cloth to remove any residue.
Paint the galvanized wrought iron with an oil-based metal paint primer. Use a two- to three-inch paintbrush and coat the entire surface well. The primer smooths the surface, providing better paint adherence later.
Wait 24 hours or according to package directions for the primer to dry completely. Paint the wrought iron with an oil-based metal paint, using a paintbrush or spray painter. Allow the first coat to dry before applying a second coat.