Chip off a small piece of the reinforced concrete. Do this with a chisel and a rock hammer. If you suspect the deterioration is deep within the concrete, drill a hole. Use an electric hammer drill for this.
Wash the piece of concrete or hole with distilled water. This removes any dust that may skew the test results.
Apply a phenolphthalein solution into the hole or the surface of the concrete piece. This measures the pH level to determine if carbonation is present. The solution is available from chemical supply companies.
Follow the directions that come with the phenolphthalein solution to determine the pH level of the concrete sample. It may remain colorless, turn purplish pink or have a rainbow of colors to choose from that indicate the carbonation level. Generally, a pH of 11.5 or less indicates carbonation is evident. This means that even a small amount of moisture may result in deterioration.
Test the concrete at a deeper level with the drill if carbonation is evident. This allows you to determine what type of repair may be necessary.