Locate the highest baseboard radiator unit in the home or the one that is the furthest away from the boiler.
Identify the bleeder screw on the unit, which is usually on the top of the unit on the right side.
Place an old towel on the floor under the bleeder screw. Turn the bleeder screw counterclockwise two to three turns using a standard screwdriver. Leave the screw open as long as you hear air hissing out. When the air has been expelled from the system, water will spurt out of the bleeder hole (in some cases water will not leak out of the bleeder hole, but the hissing sound will stop). Close the bleeder screw at that moment by turning it clockwise until it is tight.
Find the isolation valves on the pipes connected to the unit. Shut off one of the valves by turning it completely clockwise. Use a pair of slip-joint pliers if the handle on the valve is hard to turn. Open the bleeder screw again and let any air exit, then close the screw. Open the isolation valve and turn off the other one. Open the bleeder screw again and let any remaining air exit the system. Open up both isolation valves.
Repeat the entire process for each baseboard radiator unit in the home.