Locate the pipe that runs between the water heater and the expansion tank.
Close the valve on the pipe between the water heater and the expansion tank.
Connect a garden hose to the drain valve on the expansion tank. Place the opposite end of the hose in a floor drain, a sink or a bucket. Take care when handling the water so you don't get scalded. Open the drain valve.
Open the air valve on the tank when water starts to flow out of the hose. Depending on how your system is set up, the air valve will be located on the side of the expansion tank, on the drain valve, or on the valve between the water heater and the expansion tank.
Close the drain valve and the air valve after the water has drained out of the expansion tank.
Open the valve on the pipe between the water heater and the expansion tank.