Measure from one side of the doorway to the other, and record this measurement on a piece of paper.
Measure along the side of the door from the place where the curve of the arch starts down to the floor, and record this measurement.
Measure the full height of the doorway arch from the center of the top to the ground, and record this measurement.
Subtract the measurement you found in Step 2 from the measurement you found in Step 3 and record it, as well. These are the measurements that you need to deliver to any trim or door manufacturer, to get the products you need.