Measure each side of the octagonal window. Add 1 inch to each side's length.
Mark each window side's measurement plus 1 inch on pre-finished wood trim that is 1-inch thick. Cut the eight pieces of trim.
Cut each end of each trim piece to 22 ½ degrees with a miter saw. When you are done, the eight pieces should fit together as neatly as a picture frame.
Apply a thin layer of wood glue to the back of one piece of trim. Press the trim piece to its corresponding side, or edge. of the window. Repeat the procedure for each other piece of trim.
Allow the glue to cure according to the directions on its packaging.