Run the dryer with a load of wet clothes just as normal -- the best way to check if the vent is blocked is to look at it while it's in action.
Climb up to the roof using a ladder. To be extra careful, have a spotter hold the ladder steady while you climb up and wait there while you work.
Inspect the vent to see if air is escaping. If no air is coming out, then your vent and/or the exhaust duct is blocked. Check the vent itself to see if it's obstructed with lint or other debris.
Wait until the dryer is finished with its cycle before disconnecting anything. If the vent isn't pushing out air, you may need to clean out the duct. Disconnect the duct from the back of the dryer and vacuum it out with a wet/dry vacuum, then do the same at the connection between the duct and the outdoor vent.