Check the boiler water source before bleeding the boiler if there does not seem to be hot water circulating. Make sure the water supply valve is turned on but use caution as the pipes will be hot.
Inspect the boiler hot water thermostat if some baseboards are hot but others are not and turn on all heating zones.
Open the air bleeder valve on the boiler line and allow a small amount of air to escape.
Close the air bleeder valve once water exits the valve.
Look at the individual feed valves if the boiler is connected to a convector or radiator and slowly and carefully open the air feed valve on each appliance. Allow a small amount of air to exit then gradually close the valve in a clockwise motion.