Select the broccoli plant you intend to use for the seeds. Do not harvest any of its parts for eating.
Mulch the plant you chose in the fall to insulate it from winter's cold.
Remove the mulch in spring. Allow the broccoli plant to develop undisturbed until its flowers fade.
Hand-pick seed pods that have dried and turned light brown in late spring to summer. According to the International Seed Saving Institute, the pods dry in progression, starting with the ones at the bottom of the plant and moving up.
Open each seed pod by hand or put several in a cloth bag. Crush them with a hammer or tenderizer to free the seeds.
Take everything out of the bag and blow the husks away.