Stand at the point where the new wall begins. For example, if the wall is a continuation of an existing building, stand at the point where the two join.
Use the building plans to ascertain the direction in which the wall travels and then mark it on the ground. For example, if the new wall heads south at 90 degrees to the existing one, use a builder's square to mark the correct direction on the ground. This line represents the outer edge of the wall.
Move along the line representing the edge of the wall until you cover a distance equal to the wall length. Mark the spot with a peg. This is an outside corner of the new wall.
Mark a line from the corner, perpendicular to the length of the wall, running toward the inner edge of the new wall. Measure a distance equivalent to the width of the wall along this line. Mark the spot with a peg. This is an inner corner of the wall.
Mark a line from the inner corner that runs parallel to the outer length and returns back to the starting point. This line ends exactly the width of the wall away from the original start point. Mark it on the ground as the final corner of the wall.